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The Institute of Technology is in a strong position to help tackle many of the most vexing scientific questions about climate change

Peter McMurry: Solving the aerosol puzzle

by Richard Broderick

In his office, mechanical engineering professor Peter McMurry pulls up a satellite image on his computer screen.

Over the thin mid-section of Central America, a large cloud tails off to the west, obscuring a swath of land and ocean far out into the Pacific.

Mechanical engineering professor Peter McMurry is researching how and why clouds form, what role anthropogenic forcing plays in cloud formation, and the secrets of aerosol systems and their role in the formation of nanoparticles that go on to serve as cloud seeds.

“See that?” he asks. “That’s smoke from a forest fire. The fact that you can see it on this image means it’s reflecting light back into space.”

The net result of that reflection, he points out, is a cooling effect: the same as caused by the haze tapering upwind into clouds on another image he calls up off the East Coast of the United States. Cloud cover, in short, is a critical component of the globe’s system of climate regulation. How and why clouds form, what role anthropogenic forcing (caused by humans) plays in cloud formation, and in particular the secrets of aerosol systems and their role in the formation of nanoparticles that go on to serve as cloud seeds are some of the primary research focuses carried on by McMurry and collaborators at the University, the National Center for Atmospheric Research (NCAR), and other institutions.

In turn, that research has led McMurry and his colleagues to develop a number of highly sophisticated instruments to measure the size and composition of aerosol particles. These instruments are being used to understand the chemical processes responsible for high rates of particle nucleation and growth that are observed in the atmosphere.

“New particle formation occurs as a result of photochemical reactions in the atmosphere that lead to the production of condensable vapors,” he explains. “Those vapors can go on to nucleate and form molecular clusters that grow into sizes that are eventually big enough to serve as seeds for cloud formation. We are trying to understand the mechanism by which these particles are produced.”

One of the earliest instruments McMurry created measures aerosol particles, individually counting nanoparticles as small as three nanometers while also evaluating the distribution of particles by size in any given sample.

Mechanical engineering professor Peter McMurry and his colleagues built the apparatus shown above to measure the moisture absorption and volatility of atmospheric nanoparticles formed by nucleation.

Currently the team, which includes University of Minnesota chemistry professor Jeffrey Roberts and NCAR researchers Fred Eisele and James Smith, is working on other instruments designed to reveal why, under certain conditions, nucleation and growth rates are so high. For example, in places like Mexico City that are covered in dense smog, nanoparticles can grow to 100 nm—big enough to seed clouds—in less than a day.

“Typically, particles are produced at rates that are orders of magnitude greater than current models predict. Once formed, freshly nucleated particles typically grow about 10 times faster than can be explained. Clearly current models don’t take into account all of the complex processes taking place in the atmosphere,” he said. “Our goal is to identify and understand those processes so they can be included in global climate models.”